The perovskite-inspired Cu 2 AgBiI 6 (CABI) material has been gaining increasing momentum as photovoltaic (PV) absorber due to its low toxicity, intrinsic air stability, direct bandgap, and a high absorption coefficient in the range of 10 5 cm −1.However, the power conversion efficiency (PCE) of existing CABI-based PVs is still seriously constrained by the …
With the aim to go beyond simple energy storage, an organic–inorganic lead halide 2D perovskite, namely 2-(1-cyclohexenyl)ethyl ammonium lead iodide (in short CHPI), was recently introduced by Ahmad et …
Request PDF | Air-Stable Lead-Free Antimony-Based Perovskite Inspired Solar Cells and Modules | Perovskite-inspired materials (PIMs) have come to the fore recently because they aim to solve a main ...
Perovskite photocatalyzed polymerization draws special attention due to its straightforward synthesis process and the ability to create advanced perovskite-polymer nanocomposites. Herein, this work employs Cs 3 Sb 2 Br 9 perovskite nanoparticles (NPs) as a lead-free photocatalyst for light-controlled atom transfer radical polymerization (ATRP).
This paper uses antimony-doped SrFeO3-δ as a model material to shed light on the relationship between structure, stability, and performance of perovskite structured oxides which are commonly used ...
Antimony (Sb) has been identified as a promising candidate for replacing toxic lead (Pb) in perovskite materials because Sb-based perovskite-like halides exhibit not only intrinsic thermodynamic stability but also a unique set of …
In this review, group VA metal halide based perovskites, namely those of bismuth (Bi) and antimony (Sb), and their derivatives with different valence states are classified based on the formulae A 3 B 2 X 9 and A 2 AgBX 6, also known …
Perovskite-inspired materials (PIMs) have come to the fore recently because they aim to solve a main issue with perovskite technology, that of the potential toxicity of lead (Pb), as well as offer alternatives to tin (Sn)-based perovskites, which are unstable. First, we introduced two cations in the precursor mixture, which improved power conversion efficiencies …
Finally, the progress made on electron transport materials used in mesoscopic perovskite solar cells, as well as normal (n–i–p) and inverted (p–i–n) planar perovskite solar cells is briefly discussed, highlighting device architecture considerations. This chapter reviews the ETL used in perovskite solar cells, emphasizing the ...
Two-Dimensional Antimony-Based Perovskite-Inspired Materials for High-Performance Self-Powered Photodetectors
One safer alternative to lead is antimony (Sb). This work focused on the fully inorganic perovskite-inspired material Cs3Sb2I9. It can be made in two different crystal structures 0D …
nitude (i.e., appreciably narrower than lead-halide perovskite photodetectors).[25,48] Aiming for the realization of the full potential of lead-free PIMs for easy-to-fabricate, self-powered, visible-light photode-tectors, in this study we investigate, for the first time, the impact of the structural dimensionality of antimony-based perovskite-
These results highlight the potential of this perovskite anode material for use in Zn 2+ batteries. Moreover, perovskites can be a potential material for the electrolytes to …
Inverted perovskite solar cells possess great potential for single or multi-junction photovoltaics. However, energy and charge losses at the interfaces limit their performance. Here we introduce p-type antimony-doped tin oxides (ATOx) combined with a self-assembled monolayer molecule as an interlayer between the perovskite and hole-transporting layers (HTL) in inverted solar cells.
Defect mitigation and device operational stability need attention to accelerate the development of air-stable and low-toxicity photovoltaics. download Download free PDF View PDF chevron_right. Enhanced Photoconversion Efficiency in Cesium-Antimony- Halide Perovskite Derivatives by Tuning Crystallographic Dimensionality. Vincenzo Pecunia. Applied Materials Today, 2020. …
Colloidal quantum dots (QDs) of lead halide perovskite have recently received great attention owing to their remarkable performances in optoelectronic applications. However, their wide applications are hindered from toxic lead element, which is not environment- and consumer-friendly. Herein, we utilized heterovalent substitution of divalent lead (Pb2+) with trivalent …
Request PDF | Size Tunable Cesium Antimony Chloride Perovskite Nanowires and Nanorods | All-inorganic perovskite nanocrystals are emergent alternative of organolead halide perovskites. Cesium ...
In this manuscript, we report lead‐free bismuth and bismuth/antimony‐based perovskite materials [Cs2AgBiBr6, Cs2AgBi0.6Sb0.4Br6, and Cs2AgBi0.6Sb0.4(Br0.278I0.722)6] nanocrystals …
strategy to introduce antimony (Sb 3+) into the crystalline lattices of CsPbI 2 Br perovskite, which can effectively regulate the growth
While solution-processable lead-halide perovskites have raised significant hopes in this regard, toxicity concerns have prompted the search for safer, lead-free perovskite-inspired materials (PIMs) with similar …
Crystal structure for cesium antimony halide perovskites with formula Cs 3 Sb 2 X 9 (X = Cl, Br, I) were based on the description of Arakcheeva et al. [] deriving from the traditional ABX 3-type perovskites with two-thirds of occupancies of B site.The trigonal phase (space group P (overline{3 }) m1, no. 164), see Figure S1(a), exists for each halogen variant …
Perovskite Solar Cells, Photovoltaic Technology, Lead-free Perovskites, Solar Cell Materials, Antimony-based Perovskites
Aiming for the realization of the full potential of lead-free PIMs for easy-to-fabricate, self-powered, visible-light photodetectors, in this study we investigate, for the first time, the impact of the structural dimensionality of antimony-based perovskite-inspired absorbers on their self-powered photodetection capabilities.
This paper uses antimony-doped SrFeO 3−δ as a model material to shed light on the relationship between the structure, stability, and performance of perovskite-structured oxides which are commonly used as cathode materials. X-ray absorption revealed that partial substitution of Fe by Sb leads to a series of changes in the local environment of the iron atom, such as a decrease …
Request PDF | Lead-free Mn-doped antimony halide perovskite quantum dots with bright deep-red emission | We reported the first synthesis of Mn ²⁺ doped Cs 3 Sb 2 Cl x /Br 9-x (0≤ x ≤9 ...
In this manuscript, we report lead-free bismuth and bismuth/antimony-based perovskite materials [Cs 2 AgBiBr 6, Cs 2 AgBi 0.6 Sb 0.4 Br 6, and Cs 2 AgBi 0.6 Sb 0.4 (Br 0.278 I 0.722) 6] nanocrystals (NCs) …
Benefitting from Synergistic Effect of Anion and Cation in Antimony Acetate for Stable CH3 NH3 PbI3 -Based Perovskite Solar Cell with Efficiency Beyond 21 October 2021 Small 17(46):e2102186
DOI: 10.1038/s41560-023-01442-1 Corpus ID: 266974016; Enhancing the efficiency and longevity of inverted perovskite solar cells with antimony-doped tin oxides @article{Li2024EnhancingTE, title={Enhancing the efficiency and longevity of inverted perovskite solar cells with antimony-doped tin oxides}, author={Jia Li and Haoming Liang and Chuanxiao …
Particularly, newly discovered formamidinium germanium-antimony halide (FA4GeSbCl12) double perovskites offer an excellent bandgap (∼1.3 eV) for solar cell (SC) applications. Therefore, in this ...
In fact, this was also the case for other layered all-inorganic antimony-halide-perovskite studies [24, 28, 31]. Consequently, considering the electronic similarity between 2D Cs 3 Sb 2 I 9 and Cs 3 Sb 2 Cl 3 I 6, the photoconversion efficiency enhancement attained with our layered films can be related to their unoriented character, which provides them with a …
To manufacture solar cells efficiently, issues with antimony-based perovskites must be resolved. In terms of solar performance, solution-processed Sb-based perovskites are best suited for the dimer phase …
The emergence of inorganic antimony (Sb)-based perovskite-inspired solar cell simultaneously overcomes the poor stability and toxicity of lead (Pb)-based perovskite solar cell.
Lead toxicity is hindering the applications of conventional lead halide perovskites (PVKs), and antimony (Sb) is a promising nontoxic Pb alternative, showing huge potential in optoelectronic devices. Herein, pure and Mn-doped Cs3Sb2Cl9 crystals are synthesized in a facile route and studied both experimentally and theoretically. All the pure and Mn-doped …
Here we introduce p-type antimony-doped tin oxides (ATOx) combined with a self-assembled monolayer molecule as an interlayer between the perovskite and hole-transporting layers (HTL) in inverted ...
Importantly, the perovskite-inspired wide-band gap light-harvesters could lead to significantly higher PCE values in multijunction solar cell configurations. However, the PCE …
The emergence of inorganic antimony (Sb)-based perovskite-inspired solar cells simultaneously overcomes the poor stability and toxicity of lead (Pb)-based perovskite solar cells. However, in addition to reducing the toxicity of the device itself, further reducing the toxicity in the preparation process is also a necessary condition for commercialization. Herein, different …
Researchers from the University of Science and Technology of China and Hefei University of Technology have developed a proof-of-concept tandem solar cell tandem solar cell by using antimony selenide (Sb2Se3) for the bottom cell and a wide-bandgap organic-inorganic hybrid perovskite material for the top cell. The device reached a power conversion efficiency …
Herein, antimony potassium tartrate (APTA) is added to perovskite precursor as a multifunctional additive that not only coordinates with unbonded lead but also inhibits the …
Regulating Exciton Diffusion in Antimony‐Based Perovskite‐Like Single Crystals toward Highly Efficient and Stable Luminescence
Lead‐free halide double perovskite (HDP) nanocrystals are considered as one of the most promising alternatives to the lead halide perovskite nanocrystals due to their unique characteristics of ...
The tandem solar cell presents a potential solution to surpass the Shockley–Queisser limit observed in single-junction solar cells. However, creating a tandem device that is both cost-effective and highly efficient poses a significant challenge. In this study, we present proof of concept for a four-terminal (4T) tandem solar cell utilizing a wide bandgap (1.6–1.8 eV) …
The emergence of inorganic antimony (Sb)-based perovskite-inspired solar cells simultaneously overcomes the poor stability and toxicity of lead (Pb)-based perovskite solar cells.
The ongoing Internet of Things revolution has led to strong demand for low-cost, ubiquitous light sensing based on easy-to-fabricate, self-powered photodetectors. While solution-processable lead-halide perovskites have raised significant hopes in this regard, toxicity concerns have prompted the search for safer, lead-free perovskite-inspired materials (PIMs) with similar …
In this study, we present proof of concept for a four-terminal (4T) tandem solar cell utilizing a wide bandgap (1.6–1.8 eV) perovskite top cell and a narrow bandgap (1.2 eV) antimony selenide ...
The electronic configuration of antimony (ns 2 ), which is similar to that of lead, was considered to impart the excellent optical and electronic properties of the parent perovskite to the ...
Download Citation | Antimony trifluoride incorporated SnO2 for high-efficiency planar perovskite solar cells | The low-cost material antimony trifluoride (SbF3) was doped into commonly used tin ...
Antimony fluoride (SbF3): A potent hole suppressor for tin(II)‐halide perovskite devices
Abstract. Perovskite-inspired materials (PIMs) have come to the fore recently because they aim to solve a main issue with perovskite technology, that of the potential toxicity of lead (Pb), as well as offer …
